3D model (JSmol)
|Molar mass||243.329 g·mol−1|
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
|what is ?)(|
The triphenylmethyl radical (often shorted to trityl radical) is a persistent radical and the first radical ever described in organic chemistry. It can be prepared by homolysis of triphenylmethyl chloride 1 by a metal like silver or zinc in benzene or diethyl ether. The radical 2 forms a chemical equilibrium with the quinoid type dimer 3 (3-triphenylmethyl-6-diphenylmethylidene-1,4-cyclohexadiene; Gomberg's dimer). In benzene the concentration of the radical is 2%.
Solutions containing the radical are yellow and when the temperature of the solution is raised the yellow color becomes more intense as the equilibrium is shifted in favor of the radical following Le Châtelier's principle.
The radical was discovered by Moses Gomberg in 1900 at the University of Michigan. He tried to prepare hexaphenylethane from triphenylmethyl chloride and zinc in benzene in a Wurtz reaction and found that the product, based on its behaviour towards iodine and oxygen, was far more reactive than anticipated. The discovered structure was used in the development of ESR spectroscopy and confirmed by it.
The correct quinoid structure for the dimer was suggested as early as 1904 but this structure was soon after abandoned by the scientific community in favor of hexaphenylethane (4). It subsequently took until 1968 for its rediscovery when researchers at the Vrije Universiteit Amsterdam published proton NMR data.
While the trityl radical forms a quinoid dimer, derivatives thereof with the appropriate substitution pattern do form dimers with a hexaphenylethane structure. X-ray studies give a bond length of 1.67 Å for hexakis(3,5-di-t-butylphenyl)ethane. Theoretical calculations on a very high level of theory indicate that van der Waals attraction between the tert-butyl groups create a potential minimum that is absent in the unsubstituted molecule. Other derivatives have been reported as the quinoid dimer