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Titanium(III) fluoride

Titanium(III) fluoride
Titanium(III) fluoride
FeF3structure.jpg
Names
IUPAC name
Titanium(III) fluoride
Other names
Titanium trifluoride
Titanous fluoride
Trifluorotitanium
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.033.379
EC Number
  • 236-732-4
Properties
TiF3
Molar mass 104.862 g/mol
Appearance violet to purple-red powder
Density 3.4 g/cm3
Melting point 1,200 °C (2,190 °F; 1,470 K)
Boiling point 1,400 °C (2,550 °F; 1,670 K)
soluble
+1300·10−6 cm3/mol
Structure
Rhombohedral, hR24
R-3c, No. 167
Hazards[1]
Main hazards Corrosive
GHS pictograms GHS05: Corrosive
GHS signal word Danger
H314
P280, P305+351+338, P310
Related compounds
Other anions
Titanium(III) bromide
Titanium(III) chloride
Titanium(III) iodide
Related compounds
Titanium(IV) fluoride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Titanium(III) fluoride (TiF3) is a inorganic compound with the formula TiF3. It is a violet solid. It adopts a perovskite-like structure such that each Ti center has octahedral coordination geometry and each fluoride ligand is doubly bridging.[2]

References

  1. ^ "Titanium(III) Fluoride". American Elements. Retrieved July 23, 2019.
  2. ^ H. Sowa; H. Ahsbahs (1998). "Pressure-Induced Octahedron Strain in VF3-Type Compounds". Acta Crystallogr. B54: 578–584. doi:10.1107/S0108768198001207.