This page uses content from Wikipedia and is licensed under CC BY-SA.

Digenite

Digenite
Digenite.jpg
Digenite from the East Colusa Mine, Butte, Montana, USA. Specimen size = 4.3 cm
General
CategorySulfide mineral
Formula
(repeating unit)
Cu9S5
Strunz classification2.BA.05e
Dana classification02.04.07.03
Crystal systemTrigonal
Crystal classHexagonal scalenohedral (3m)
H-M symbol: (3 2/m)
Space groupR3m
Identification
Formula mass146.45 g/mol
ColorBlue to black
Crystal habitPseudocubic crystals are rare, usually as intergrowths with other copper sulfides
Cleavage{111} (observed in synthetic material)
FractureConchoidal
TenacityBrittle
Mohs scale hardness2.5 to 3
LusterSubmetallic to metallic
StreakBlack
DiaphaneityOpaque
Specific gravity5.5 to 5.7 observed, 5.628 calculated
Optical propertiesReflectivity: 21.6 at 540 nm
Other characteristicsDistinctly blue in polished sections
References[1][2][3][4]

Digenite is a copper sulfide mineral with formula: Cu9S5. Digenite is a black to dark blue opaque mineral that crystallizes with a trigonal - hexagonal scalenohedral structure. In habit it is usually massive, but does often show pseudo-cubic forms. It has poor to indistinct cleavage and a brittle fracture. It has a Mohs hardness of 2.5 to 3 and a specific gravity of 5.6. It is found in copper sulfide deposits of both primary and supergene occurrences. It is typically associated with and often intergrown with chalcocite, covellite, djurleite, bornite, chalcopyrite and pyrite. The type locality is Sangerhausen, Thuringia, Germany, in copper slate deposits.[1]

Occurrence

Digenite occurs in the transitional zone of supergene oxidation of primary sulfide ore deposits, at the interface between the upper and lower saprolite ore zones. It is rarely an important mineral for copper ores, as it is more usually replaced by chalcocite further up in the weathering profile, and is a minor weathering product of primary chalcopyrite. Natural digenite always contains a small amount of iron and is considered to be stable only in the Cu-Fe-S system.[5]

In the Deflector and Deflector West Cu-Au lode deposits of the Gullewa Greenstone Belt, Western Australia, digenite is an important constituent of the transitional Cu-Au ore. However, it is difficult to treat metallurgically and remains a refractory ore type. In this locality digenite is found with covellite, chalcocite and bornite.

It was first described in 1844 from the type locality of Sangerhausen, Saxony-Anhalt, Germany. The name is from the Greek digenus meaning of two origins in reference to its close resemblance with chalcocite and covellite.[1]

Polymorphs of digenite

There are three polymorphs of digenite, high, metastable and low.[6] There is a complete solid solution series between high digenite and berzelianite Cu2−xSe (x~0.12).[7]

High digenite is stable above 73 °C, with space group Fm3m and unit cell parameters a=5.57 Å and Z=1 for formula Cu7.2−xS4. High digenite is isostructural with bornite Cu5FeS4.[6]

Metastable digenite forms on cooling from 73 °C. It appears to be isometric with space group Fd3m and a=27.85 Å. This symmetry, however, is due to twinning of fine domains with rhombohedral symmetry, trigonal -3m, point group R-3m,[6] a = 3.92 Å, c = 48 Å, Z =15 for formula Cu1.8S.[1] Metastable digenite changes with time to stable low temperature digenite[6] or a mixture of anilite Cu7S4 and djurleite Cu31S16.[5]

Low digenite is isometric, space group Fd3m and a=27.85 Å, i.e. the same as the apparent isometric symmetry of the metastable polymorph,[6] Z=4 for formula Cu1.8S.

References

  1. ^ a b c d [www.mindat.org]
  2. ^ Gaines et al (1997) Dana's New Mineralogy Eighth Edition, Wiley
  3. ^ [rruff.geo.arizona.edu] Handbook of Mineralogy
  4. ^ [webmineral.com] Webmineral data
  5. ^ a b American Mineralogist (1970) 55:106
  6. ^ a b c d e American Mineralogist (1963) 48:110
  7. ^ Canadian Mineralogist (2008) 46: 219-231
  • Palache, C., H. Berman, and C. Frondel (1944) Dana’s system of mineralogy, (7th edition), v. I, pp. 180–182.